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| General Description | 1,4-dichlorobutane, also known as 1,4-DCB, is a chemical compound with the formula C4H8Cl2. It is a colorless liquid with a sharp, pungent odor and is insoluble in water but soluble in organic solvents. 1,4-DCB is primarily used as an intermediate in the production of other chemicals, including pharmaceuticals and pesticides. It is also used as a solvent and as a reagent in organic synthesis. The compound is classified as a chlorinated hydrocarbon and is considered to be toxic to the environment, with potential harmful effects on aquatic organisms. It is important to handle and dispose of 1,4-dichlorobutane with care to minimize its impact on human health and the environment. | 
InChI:InChI=1/C4H8Cl2/c1-2-3-4(5)6/h4H,2-3H2,1H3
We made use of four methods for determin...
The photochlorinations of the n-butyl, n...
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In contrast to photolysis or thermal dec...
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The Diels-Alder reactions of trichloroph...
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The title reactions of HOOC(CH2)nCOOH ac...
Mesoporous TiO2–carbon nanocomposites we...
The invention discloses a preparation me...
The invention discloses a continuous met...
The invention discloses a quinoline deri...
The invention provides a 1,4-dichlorobut...
 
                                            
                                        ethene
 
                                 
                                            
                                        1,2-dichloro-ethane
 
                                 
                                            
                                        1,2-dichlorobutane
 
                                 
                                            
                                        1,2-dichlorohexane
 
                                 
                                            
                                        1,2-dichlorooctane
 
                                 
                                            
                                        1,2-dichlorodecane
 
                                 
                                            
                                        ethylbenzene
 
                                 
                                            
                                        1,4-dichlorobutane
| Conditions | Yield | 
|---|---|
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    dibenzoyl peroxide; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 100 ℃;
                                                            
                                                Product distribution;
                                                            
                                                Mechanism;
                                                            
                                            
                                         | 
 
                                            
                                        n-Butyl chloride
 
                                 
                                            
                                        1,1-dichlorobutane
 
                                 
                                            
                                        1,3-dichlorobutane
 
                                 
                                            
                                        1,2-dichlorobutane
 
                                 
                                            
                                        1,4-dichlorobutane
| Conditions | Yield | 
|---|---|
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    sulfuryl dichloride; 
                                            
                                            
                                                zeolite NaX; 
                                            
                                            
                                                
                                                            for 2h;
                                                            
                                                Heating;
                                                            
                                                Irradiation;
                                                            
                                            
                                         | 6 % Chromat. 23 % Chromat. 46 % Chromat. 25 % Chromat. | 
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    sulfuryl dichloride; 
                                            
                                            
                                                zeolite NaX; 
                                            
                                            
                                                
                                                            for 2h;
                                                            
                                                Product distribution;
                                                            
                                                Heating;
                                                            
                                                Irradiation;
                                                            
                                            
                                         | 6 % Chromat. 23 % Chromat. 46 % Chromat. 25 % Chromat. | 
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    norborn-2-ene; N-chlorohexamethyldisilazane; trans-di-O-tert-butyl hyponitrite; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 44.9 ℃;
                                                            
                                                            for 1h;
                                                            
                                                Product distribution;
                                                            
                                                Mechanism;
                                                            
                                                further reagent, time;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    chlorine; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                tetrachloromethane; 
                                            
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                Product distribution;
                                                            
                                                other solvents, other temperatures;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    phenylchloroiodonium chloride; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                tetrachloromethane; 
                                            
                                            
                                            
                                                
                                                            at 30 ℃;
                                                            
                                                Product distribution;
                                                            
                                                Mechanism;
                                                            
                                                Irradiation;
                                                            
                                                relative rate const., the correlation analysis, subst. phenylchloroiodonium chloride as reagents;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    N-chloropiperidine; 2,2'-azobis(isobutyronitrile); 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                trifluoroacetic acid; 
                                            
                                            
                                            
                                                
                                                            at 30 ℃;
                                                            
                                                Product distribution;
                                                            
                                                Rate constant;
                                                            
                                                Irradiation;
                                                            
                                                relative rate constants, position selectivity, substrate selectivity;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    chlorine; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                benzene; 
                                            
                                            
                                            
                                                
                                                            at -10.1 ℃;
                                                            
                                                Product distribution;
                                                            
                                                dependence of the selectivity of chlorination on the conc. of benzene;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    N-chloropiperidine; 2,2'-azobis(isobutyronitrile); 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                trifluoroacetic acid; 
                                            
                                            
                                            
                                                
                                                            at 30 ℃;
                                                            
                                                            for 3h;
                                                            
                                                Product distribution;
                                                            
                                                Rate constant;
                                                            
                                                Irradiation;
                                                            
                                                other objects - relative reactivities and relative rate constants for the various positions of chlorination;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    chlorine; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                1,2-dichloro-benzene; 
                                            
                                            
                                            
                                                
                                                            at -20 - 50 ℃;
                                                            
                                                Product distribution;
                                                            
                                                Mechanism;
                                                            
                                                Ratio of products and rate constants; different concentrations of o-dichlorobenzene.;
                                                            
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    chlorine; 
                                            
                                            
                                                
                                            
                                            
                                                
                                            
                                         | |
| 
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    sulfuryl dichloride; dibenzoyl peroxide; 
                                            
                                            
                                                
                                            
                                            
                                                
                                            
                                         | 
 
                                tetrahydrofuran
 
                                Dichloromethylsilane
 
                                phosgene
 
                                (E)-3-Ureido-but-2-enoic acid ethyl ester
 
                                hexahydro-pyrazolo[1,2-a]pyridazine
 
                                octahydro-pyridazino[1,2-a]pyridazine
 
                                1,4-diaminobutane
 
                                1-phenyl-1-cyclopentanecarbonitrile
