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9-Fluorenone

  • Product Name: 9-Fluorenone
  • CAS: 486-25-9
  • Purity:
  • Appearance: yellow flakes, chips or crystalline powder

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China cas 486-25-9 factory wholesale 9-Fluorenone at affordable price

  • Molecular Formula:C13H8O
  • Molecular Weight:180.206
  • Appearance/Colour:yellow flakes, chips or crystalline powder 
  • Vapor Pressure:8.01E-05mmHg at 25°C 
  • Melting Point:80-83 °C(lit.) 
  • Refractive Index:1.667 
  • Boiling Point:341.499 °C at 760 mmHg 
  • Flash Point:144.142 °C 
  • PSA:17.07000 
  • Density:1.244 g/cm3 
  • LogP:2.89800 

9-Fluorenone(Cas 486-25-9) Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 3934, 1995 DOI: 10.1021/jo00118a002Synthetic Communications, 6, p. 285, 1976 DOI: 10.1080/00397917608063524

Purification Methods

Crystallise 9-fluorenone from absolute EtOH, MeOH or *benzene/pentane. [Ikezawa J Am Chem Soc 108 1589 1986.] Also recrystallise it twice from toluene and sublime it in a vacuum [Saltiel J Am Chem Soc 108 2674 1986]. It can be distilled under high vacuum. [Beilstein 7 H 465, 7 III 2330, 7 IV 1629.]

General Description

9-Fluorenone is a polycyclic aromatic ketone with a planar structure, serving as a core component in the synthesis of chiral bent cyclophanes and polyaryl derivatives. It exhibits notable optoelectronic properties, including high fluorescence quantum yields when incorporated into rigid cyclophane structures, and can be selectively functionalized through metal-catalyzed C–O bond activation for applications in materials science, such as organic light-emitting devices and liquid crystals.

Application

9-Fluorenone has been extensively used as a precursor to synthesize a variety of organic electronic materials. Some of the general examples are:Synthesis of host for the blue and green phosphorescent organic light emitting diodes (PHOLEDs).Synthesis of fluorene-based molecular motors.Synthesis of open-shell Chichibabin′s hydrocarbons as potential organic spintronic materials.It also acts as a sensitizer in the formation of picene via photosensitization of 1,2-di(1-naphthyl)ethane.

Definition

ChEBI: The simplest member of the class fluoren-9-ones that is 9H-fluorene bearing an oxo substituent at position 9.

InChI:InChI=1/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H

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Huntress,Hershberg,Cliff

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Substituent and pH Effects on the Hydrolysis Modes of 9-(dinitromethyl)-9-alkoxylfluorenes

Hoz, Shmaryahu,Perach, Sara Sima

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The hydrolysis of 9-(dinitromethyl)-9-al...

On the mechanism of the directed ortho and remote metalation reactions of N,N-dialkylbiphenyl 2-carboxamides

Tilly, David,Fu, Jian-Min,Zhao, Bao-Ping,Alessi, Manlio,Castanet, Anne-Sophie,Snieckus, Victor,Mortier, Jacques

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"Chemical Equation Presented" A study co...

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Metz

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C-OH bond cleavage initiated by electron transfer: Electroreduction of 9-fluorenol

Mendkovich, Andrey S.,Syroeshkin, Mikhail A.,Nasybullina, Darya V.,Mikhailov, Mikhail N.,Gultyai, Vadim P.,Elinson, Mikhail N.,Rusakov, Alexander I.

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Cyclic voltammetry, chronoamperometry, c...

Novel photo-induced coupling reaction of 9-fluorenylidenemalononitrile with 10-methyl-9,10-dihydroacridine

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Evidence for rhenaphenanthrene formation and its conversion to fluorenone

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Thermal and photochemical 1,3-dipolar cycloaddition of a sulfine (Fluorenethione S-oxide) to the strained triple bond of cyclooctyne

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486-25-9 Process route

9H-fluoren-9-yl bromide
1940-57-4

9H-fluoren-9-yl bromide

C<sub>9</sub>H<sub>7</sub>N<sub>2</sub>O<sub>3</sub><sup>(1-)</sup>*Ag<sup>(1+)</sup>
107985-36-4

C9H7N2O3(1-)*Ag(1+)

9-fluorenone
486-25-9,952573-42-1

9-fluorenone

(Z)-2,3-bis(4-methoxyphenyl)but-2-enedinitrle
4680-92-6

(Z)-2,3-bis(4-methoxyphenyl)but-2-enedinitrle

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

9-fluorenyl(4-methoxyphenyl)(nitro)acetonitrile
107960-28-1

9-fluorenyl(4-methoxyphenyl)(nitro)acetonitrile

Conditions
Conditions Yield
In benzene; for 55h; Ambient temperature;
45%
4.5%
26%
37%
(9-Hydroxy-9H-fluoren-9-yl)-phosphonic acid diisopropyl ester

(9-Hydroxy-9H-fluoren-9-yl)-phosphonic acid diisopropyl ester

9-fluorenone
486-25-9,952573-42-1

9-fluorenone

diisopropyl hydrogenphosphonate
1809-20-7

diisopropyl hydrogenphosphonate

Conditions
Conditions Yield
With triethylamine; Rate constant; other reagents (n-butyl- and t-butylamine);

486-25-9 Upstream products

  • 56-23-5
    56-23-5

    tetrachloromethane

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    18083-81-3

    methyl 9-fluoreneglyoxylate

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    860588-41-6

    9,9'-bis-(2-nitro-phenylsulfanyl)-[9,9']bifluorenyl

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    93-59-4

    Perbenzoic acid

486-25-9 Downstream products

  • 100-52-7
    100-52-7

    benzaldehyde

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    64436-62-0

    9-(pyridin-2-yl)-9H-fluoren-9-ol

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    42074-47-5

    9-(2-chloro-phenyl)-fluoren-9-ol

  • 7029-48-3
    7029-48-3

    9-ethyl-9H-fluoren-9-ol

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