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Flammability and Explosibility |
Highlyflammable |
Purification Methods |
1,Possible impurity is 1,1,5,5-tetramethyl-3-trimethylsiloxytrisiloxane b 154-155o/733mm. Fractionate it, collect fractions boiling below 80o and re-fractionate it. Its purity can be analysed by alkaline hydrolysis and measuring the volume of H2 liberated followed by gravimetric estimation of silica in the hydrolysate. It is unchanged when stored in glass containers in the absence of moisture for 2-3 weeks. Small amounts of H2 are liberated on long storage. Care should be taken when opening a container due to pressure developed. [Speier et al. J Am Chem Soc 79 974 1958, Emeléus & Smythe J Chem Soc 609 1958, IR: Kriegsmann Z Anorg Chem 299 78 1959, Beilstein 4 IV 3991.] |
InChI:InChI=1/C4H14OSi2/c1-6-5-7(2,3)4/h6H2,1-4H3
Described herein are methods for making ...
The invention discloses a treatment meth...
A spherosilicate dendrimer (DMS-1) with ...
Silicone core dendrimers bearing termina...
C11H18O2Si
1,1,3,3-Tetramethyldisiloxane
Hexamethylcyclotrisiloxane
octamethylcyclotetrasiloxane
1-methyl-1-phenylethyl alcohol
dimethylsilanone
Conditions | Yield |
---|---|
In
nonane;
at 160 ℃;
Rate constant;
Kinetics;
Thermodynamic data;
ΔE(excit.);
|
dimethylmonochlorosilane
1,1,3,3-Tetramethyldisiloxane
Conditions | Yield |
---|---|
With
water;
|
|
With
hydrogenchloride; water;
at -10 - 50 ℃;
for 4h;
|
Dichloromethylsilane
methylmagnesium chloride
dimethylmonochlorosilane
iododimethylsilane
1,3-bis(glycidyloxypropyl)-1,1,3,3-tetramethyldisiloxane
1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane
1,3-Diheptyl-1,1,3,3-tetramethyl-disiloxan
1,1,3,3-tetramethyl-1-(2-phenylpropyl)disiloxane