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1,4-Dihydroxyanthraquinone (Quinizarin)

  • Product Name: 1,4-Dihydroxyanthraquinone (Quinizarin)
  • CAS: 81-64-1
  • Purity:
  • Appearance: orange to red-brown crystalline powder

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Factory supply good quality 1,4-Dihydroxyanthraquinone (Quinizarin) 81-64-1 with stock

  • Molecular Formula:C14H8O4
  • Molecular Weight:240.215
  • Appearance/Colour:orange to red-brown crystalline powder 
  • Vapor Pressure:1 mm Hg ( 196.7 °C) 
  • Melting Point:198-199 °C(lit.) 
  • Refractive Index:1.732 
  • Boiling Point:465.3 °C at 760 mmHg 
  • PKA:pK (18°) 9.51 
  • Flash Point:249.3 °C 
  • PSA:74.60000 
  • Density:1.54 g/cm3 
  • LogP:1.87320 

1,4-DIHYDROXYANTHRAQUINONE(Cas 81-64-1) Usage

Preparation

commonly known as Quinizarin. (a) Boric acid, boric acid and mercury, boric acid and nitrous acid or nitrous acid and mercury in the presence of Anthracene-9,10-dione with sulfuric acid; (b) In the presence of boric acid and nitrous acid, treated with sulfuric acid ?1-Hydroxyanthracene-9,10-dione or 2-Hydroxyanthracene-9,10-dione, (c)In the presence of boric acid, treated with sulfuric acid 1-Hydroxy-4-nitroanthracene-9,10-dione?or?1,4-Dichloroanthracene-9,10-dione?; (d) in the Boric acid and where did in the presence of sulfuric acid, Phthalic anhydride and 4-Chlorophenol?or Hydroquinone condensation, closed loop.

Synthesis Reference(s)

Synthesis, p. 633, 1974 DOI: 10.1055/s-1974-23387Tetrahedron Letters, 28, p. 1533, 1987 DOI: 10.1016/S0040-4039(01)81035-2

Flammability and Explosibility

Nonflammable

Safety Profile

Poison by intravenous route. Moderately toxic by intraperitoneal route. Mutation data reported. An eye irritant. A weak allergen. When heated todecomposition it emits acrid smoke and irritating fumes.

Purification Methods

Crystallise quinizarin from glacial acetic acid. [Beilstein 8 H 450, 8 IV 3260.]

Definition

ChEBI: A dihydroxyanthraquinone having the two hydroxy substituents at the 1- and 4-positions; formally derived from anthraquinone by replacement of two hydrogen atoms by hydroxy groups

General Description

1,4-Dihydroxyanthraquinone is an organic dye molecule with an aromatic structure. It is a derivative of anthraquinone bearing hydroxyl moieties. They may find uses in pharmacological, biochemical and dye industries. Anthraquinone dye are resistant to degradation.

Properties and Applications

orange. Orange red powder. Insoluble in water, soluble in ether, in strong base in certain solubility, but soluble in organic solvent oil, etc. In concentrated sulfuric acid in green yellow fluorescence. Mainly used for oil coloring. Also used in all kinds of plastic and resin, light industry products coloring.

InChI:InChI=1/C14H8O4/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6,15-16H

81-64-1 Relevant articles

Clean process for synthesizing 1, 4-dihydroxy anthraquinone

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81-64-1 Process route

reactive blue 19
2580-78-1

reactive blue 19

3-aminophthalic acid
5434-20-8,857040-74-5

3-aminophthalic acid

1,4-dihydroxy-9,10-anthracenedione
81-64-1,103220-12-8

1,4-dihydroxy-9,10-anthracenedione

1,4-diamino-9,10-dioxo-9,10-dihydro-anthracene-2-sulfonic acid
4095-85-6

1,4-diamino-9,10-dioxo-9,10-dihydro-anthracene-2-sulfonic acid

1-amino-9,10-anthracenedione
82-45-1

1-amino-9,10-anthracenedione

benzene-1,2-dicarboxylic acid
88-99-3,73607-73-5

benzene-1,2-dicarboxylic acid

Conditions
Conditions Yield
With chitosan/polyaniline/CdS nanocomposite; for 2h; pH=6; pH-value; Catalytic behavior; Kinetics; Irradiation;
anthracene-1,4,9,10-tetraone
1709-63-3

anthracene-1,4,9,10-tetraone

1,4-dihydroxy-9,10-anthracenedione
81-64-1,103220-12-8

1,4-dihydroxy-9,10-anthracenedione

benzene-1,2-dicarboxylic acid
88-99-3,73607-73-5

benzene-1,2-dicarboxylic acid

Conditions
Conditions Yield
With water; Product distribution; Thermodynamic data; Mechanism; ΔrH0m, ΔrG0m;

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